Interaction between Hydrofluorosilicic Acid and 1,10-Phenanthroline: Hydrolytic Stability of Chelate Complexes of Silicon Tetrafluoride with Bidentate N-Donors

Gel’mbol’dt, V. O.; Anisimov, V. Yu.; Fonar, M. S.

dc.contributor.author	Gel’mbol’dt, V. O.	en
dc.contributor.author	Anisimov, V. Yu.	en
dc.contributor.author	Fonar, M. S.	en
dc.date.accessioned	2020-04-02T08:19:03Z
dc.date.available	2020-04-02T08:19:03Z
dc.date.issued	2016
dc.identifier.citation	Gel’mbol’dt V. O, Anisimov V. Yu, Fonar’ M. S. Interaction between Hydrofluorosilicic Acid and 1,10-Phenanthroline: Hydrolytic Stability of Chelate Complexes of Silicon Tetrafluoride with Bidentate N-Donors // Russian journal of inorganic chemistry. – 2016. – Vol. 61, N. 7. P. 822–825.	en
dc.identifier.uri	https://repo.odmu.edu.ua:443/xmlui/handle/123456789/6825
dc.description.abstract	Hexafluorosilicate (LH2)SiF6 and the cis-[SiF4(L)] chelate complex characterized by 19F NMR are products of reaction between hydrofluorosilicic acid and 1,10-phenanthroline (L). XRD findings show that the structure of (LH2)SiF6 is stabilized by NH⋅⋅⋅F hydrogen bonds (N⋅⋅⋅F 2.618(4), 2.676(4) Å) and CH⋅⋅⋅F contacts. The relative resistance of the cis-[SiF4(L)] complex to hydrolysis is associated with the chelate effect.	en
dc.language.iso	en	en
dc.subject	Hexafluorosilicate	en
dc.subject	Hydrofluorosilicic Acid	en
dc.subject	Hydrolytic Stability	en
dc.subject	Chelate Complexes	en
dc.title	Interaction between Hydrofluorosilicic Acid and 1,10-Phenanthroline: Hydrolytic Stability of Chelate Complexes of Silicon Tetrafluoride with Bidentate N-Donors	en
dc.type	Article	en