Tetrabenzylcyclen as a receptor for fluoride

dc.contributor.author	Gelmboldt, V. O.	en
dc.contributor.author	Ganin, E. V.	en
dc.contributor.author	Basok, S. S.	en
dc.contributor.author	Kulygina, E. Yu.	en
dc.contributor.author	Botoshansky, M. M.	en
dc.contributor.author	Kravtsov, V. Ch.	en
dc.contributor.author	Fonari, M. S.	en
dc.date.accessioned	2019-12-12T11:25:50Z
dc.date.available	2019-12-12T11:25:50Z
dc.date.issued	2011
dc.identifier.citation	Tetrabenzylcyclen as a receptor for fluoride / V. O. Gelmboldt, E. V. Ganin, S. S. Basok and others // The Royal Society of Chemistry. – 2011. – № 13. – P. 3682–3685.	en
dc.identifier.uri	https://repo.odmu.edu.ua:443/xmlui/handle/123456789/6106
dc.description.abstract	A tetraazacyclic ligand, tetrabenzylcyclen (L), was synthesized using an improved method with a higher yield by treatment of cyclen with benzylchloride in the presence of potassium carbonate. The reaction of L with an aqueous solution of fluorosilicic acid yielded a mixed-anionic salt with the composition [H3L][F][SiF6]$4H2O (1). The single crystal X-ray study revealed that the macrocyclic trication essentially changes the conformation compared to the free ligand in order to tightly accommodate the fluoride inside and to keep the hexafluorosilicate anions and water molecules outside in the solid state complex.	en
dc.language.iso	en	en
dc.subject	tetrabenzylcyclen	en
dc.subject	benzylchloride	en
dc.subject	mixed-anionic salt	en
dc.subject	water molecules	en
dc.title	Tetrabenzylcyclen as a receptor for fluoride	en
dc.type	Article	en