Synthesis and Structure of N(Hydroxyethyl)ethylenediammonium Sulfite Monohydrate

Khoma, R. E.; Gelmboldt, V. O.; Shishkin, O. V.; Baumer, V. N.; Puzan, A. N.; Ennan, A. A.; Rakipov, I. M.

Synthesis and Structure of N(Hydroxyethyl)ethylenediammonium Sulfite Monohydrate

Khoma, R. E.; Gelmboldt, V. O.; Shishkin, O. V.; Baumer, V. N.; Puzan, A. N.; Ennan, A. A.; Rakipov, I. M.

URI: http://repo.odmu.edu.ua:80/xmlui/handle/123456789/4183

Date: 2014

Abstract:

A reaction between sulfur(IV) oxide and aqueous N(2hydroxyethyl)ethylenediamine yields onium sulfite of composition (HOCH2CH2NH2CH2CH2NH3)SO3 ⋅ H2O, which has been characterized by Xray diffraction, IR spectroscopy, and mass spectrometry. The threedimensional structure of the salt is stabilized by numerous hydrogen bonds, such as NH⋅⋅⋅O and OH⋅⋅⋅O.

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