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Dibenzoxazepine Anodic Determination and Removal on CuS Nanoparticles: A Theoretical Insight
Tkach, V. V.; Kushnir, M. V.; Sílvio C. de Oliveira; Biryuk, I. G.; Sykyrytska, T. B.; Ivanushko, Ya. G.; Yagodynets, P. I.; Adriano O. da Silva; Derevianko, N. P.; Zavhorodnii, M. P.; Odyntsova, V. M.; Krasko, M. P.; Shevchenko, I. M.; Lavrinenko, V. M.; Yermak, O. T.; Niyazov, L. N.; Musayeva, D. M.; Kosimov, X.; Jabborova, O.; Gulandom Sagdullayeva; Sharipova, E.; Morozova, T. V.; Mudrak, O. V.; Garcia, Ja. R.; José Inácio Ferrão da Paiva Martins; Kormosh, Zh. O.; Grekova, A. V.; Burdina, Ia. F.; Lavrik, R. V.
For the first time, the electroanalytical system for the electrochemical determination and removal of dibenzoxazepine chemical warfare agent on CuS-modified anode has been given. Two oxidation scenarios, including the electropolymerization and N-oxidation, are possible for dibenzoxazepine. Either way, both dibenzoxazepine and its N-oxide will be removed from the environment towards the polymer phase. The analysis of the electroanalytical process using linear stability theory and bifurcation analysis confirms that the steady-state stability allows us to use this process for both electroanalytical and electrocatalytic purposes.
